Synthesis, Characterization and Activity Test of Natural Zirconium Zeolite (Zr-ZA) Catalyst in The Esterification Reaction of Glycerol with Acetic Acid Anhydride

Didik Krisdiyanto, Tutik Farihah, Hikmah Supriyati

Abstract


Synthesis of Zr-ZA catalyst used as catalyst for esterification reaction of glycerol with acetic acid anhydrous has been done. Catalysts are characterized using an infrared spectrophotometer, X-ray diffraction, and measurement of surface acidity, while reaction products are characterized using a gas chromatography-mass spectrometer. Effect of catalyst acidity, reaction time and re-addition of acetic acid anhydrous studied by glycerol conversion and selectivity value of triacetin were yielded. Infra-red spectrophotometer and X-ray diffraction analysis of the catalyst showed that the synthesized catalyst was zirconium zeolite (Zr-ZA), while esterification analysis using a gas chromatography-mass spectrometer showed a triacetin product.

Keywords


Glycerol; Triacetin; Acetic Acid Anhydrous

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References


Alzeer, J., Hadeed, K.A. (2021). Halal Certification of Food, Nutraceuticals, and Pharmaceuticals in the Arab World. In: Laher, I. (eds) Handbook of Healthcare in the Arab World. Springer, Cham.

Appleby, D. (2003). The impact of biodiesel production on the glycerine market. Oral precentation of Procter & Gamble at American Oil Chemist Society, Champain, Illinois.

Beck, J.S. Vartuli, J.C. Roth, W.J. Leonowicz, M.E. Kresge, C.T. Schmitt, K. D. Chu, C.T.W Olson, D.H. Sheppard E. W., McCullen, S.B. Higgins, J.B. Schlenker J.L. A new family of mesoporous molecular sieves prepared with liquid crystal templates J. Am. Chem. Soc., 114 (1992), pp. 10834-10843

Comelli, N.A., E.N. Ponzi, M.I. Ponzi. (2006). ?- Pinene Isomerization to Camphene Effect of Thermal Treatment on Sulfated Zirconia. Chemical Engineering Journal, 117 (2): 93–99

Dewajani H, Zamrudy W, Saroso H, Paramarta S, Mulya W (2019), Conversion of Crude Glycerol from by-Product Biodiesel into Bio-additive of Fuel through Acetylation Reaction based on Modified Zeolite Catalyst, Alchemy volume 7 no 2 page 46-52

Fiume MZ, (2003)., Cosmetic Ingredients Review Expert Panel. Final report on the safety assessment of triacetin. International Journal of Toxicology.; 22 Suppl 2:1-10.

Gama, N., Santos, R., Godinho, B. (2019). Triacetin as a Secondary PVC Plasticizer. J Polym Environ 27, 1294–1301

Gültekin, F., Çeker, O. Elgün, A., Gürbilek., M, ?im?ek, M., Oral, R., Köse, S., Türker, S., Döndüren, H., Ünaldi, M., Küçüköner, E., Yetim H, Aydin, A., Dede B., Özmen, I., Ba?ayi?it, L., Cengiz, M., Tilki, T., Akin, S., (2020)., Evaluation of Food Additives in Terms of Istihalah., Jurnal of Halal Life tyle., volume 2 issue 1 page 1-13

Ghoreishi, k b. (2013). Sol-gel sulphated silica as a catalyst for glycerol acetylation with acetic acid. Journal of Science and Technology, 5(1).

Hendayana, S. (1994). Kimia Analitik Instrumen Edisi Kesatu. Semarang: IKIP Semarang Press.

Jiang M, Liu S, Du X, Wang Y, (2010). Physical properties and internal microstructures of films made from catfish skin gelatin and triacetin mixtures, Food Hydrocolloids, Volume 24, Issue 1, Pages 105-110,

Nawrocki, J. Rigney, M. McCormick, A. Carr, P.W. (1993)., Chemistry of zirconia and its use in chromatography, Journal of Chromatography A, Volume 657, Issue 2, Pages 229-282,

Nuryoto, Sulistyo, H., Rahayu S.S., Sutijan., (2010). Uji Performa Katalisator Resin Penukar Ion Untuk Pengolahan Hasil Samping Pembuatan Biodiesel Menjadi Triacetin. Seminar Rekayasa Kimia Dan Proses

Ogawa T, Moriwaki N, Fujii R, (1992). Triacetin as Food Additive in Gummy Candy and Other Foodstuffs on The Market. The Kitasato Archives of Experimental Medicine. Apr;65(1):33-44. PMID: 1479781.

Reddy, Padigapati. S., Sudarsanam, P., Raju, G., & Reddy, B. M. (2010). Synthesis of bioadditives: Acetylation of glycerol over zirconia-based solid acid catalysts. Catalyst Communications, 11 (15), 1224–1228.

Setyaningsih, L., Ali, I. A., Chafidz, A., Septiyan, S., and Eka, P. A. (2020). Triacetin Production by Selective Esterification of Glycerol over Activated Zeolite and Lewatite as Catalyst. Materials Science Forum, 988, 122–127.

Silva. Leonardo N, Valter L.C, Goncalves, Claudio J.A. Mota., (2010). Catalytic Acetylation of Glycerol With Acetic Anhydride. Catalysis Communications - CATAL COMMUN. 11. 1036-1039. 10.1016/j.catcom.2010.05.007.

Sastrohamidjojo. H (2007). Spektroskopi. Yogyakarta: Liberty.

Tanabe K., Yamaguchi T., (1994) Acid-base bifunctional catalysis by ZrO2 and its mixed oxides, Catalysis Today, Volume 20, Issue 2, Pages 185-197,

Teterycz, H., Klimkiewicz, R., Laniecki, M.. (2003). The Role of Lewis Acidic Centers in Stabilized Zirconium Dioxide. Applied Catalysis A: General. 249. 313-326.

Widayat, Satriadi H, Abdullah, Ika Windrianto K. Handono. (2013). Proses Produksi Triasetat dari Gliserol dengan Katalis Asam Sulfat. Jurnal Teknik Kimia Indonesia. 12. 192. 10.5614/jtki.2013.12.1.3.

Yanti, N.R., Heryani, H., Putra, M.D., Nugroho, A., (2019). Triacetin Production from Glycerol Using Heterogeneous Catalysts Prepared From Peat Clay. International Journal of Technology. Volume 10(5), pp. 970-978




DOI: https://doi.org/10.14421/biomedich.2023.121.61-67

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Copyright (c) 2022 Didik Krisdiyanto, Tutik Farihah, Hikmah Supriyati



Biology, Medicine, & Natural Product Chemistry
ISSN 2089-6514 (paper) - ISSN 2540-9328 (online)
Published by Sunan Kalijaga State Islamic University & Society for Indonesian Biodiversity.

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